Iron catalyzed enantioselective sulfa-Michael addition: a four-step synthesis of the anti-asthma agent Montelukast-Reference-Cited by-同舟云学术

Iron catalyzed enantioselective sulfa-Michael addition: a four-step synthesis of the anti-asthma agent Montelukast

Published:2014 Issue:6 Volume:5 Page:2200-2204
ISSN:2041-6520
Container-title:Chem. Sci.
language:en
Short-container-title:Chem. Sci.

Author:

White James D.¹²³,Shaw Subrata¹²³

Affiliation:

1. Department of Chemistry

2. Oregon State University

3. Corvallis, USA

Abstract

Asymmetric conjugate addition of thiols to acyclic α,β-unsaturated ketones catalyzed by an iron(iii)–salen complex gives β-thioketones in high enantiomeric excess.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/SC/C4SC00051J

Reference42 articles.

1. Enantioselective Conjugate Additions

2. Recent Advances in Catalytic Enantioselective Michael Additions

3. Asymmetric Sulfa-Michael Additions

4. A novel C-5′ substituted cinchona alkaloid-derived catalyst promotes additions of alkyl thiols to nitroolefins with excellent enantioselectivity

5. Squaramide-catalysed enantio- and diastereoselective sulfa-Michael addition of thioacetic acid to α,β-disubstituted nitroalkenes

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