Speciation and dipole reorientation dynamics of glass-forming liquid electrolytes: Li[N(SO2CF3)2] mixtures of 1,3-propane sultone or tetrahydrothiophene-1,1-dioxide-Reference-Cited by-同舟云学术

Speciation and dipole reorientation dynamics of glass-forming liquid electrolytes: Li[N(SO₂CF₃)₂] mixtures of 1,3-propane sultone or tetrahydrothiophene-1,1-dioxide

Published:2024 Issue: Volume: Page:
ISSN:1359-6640
Container-title:Faraday Discussions
language:en
Short-container-title:Faraday Discuss.

Author:

Umebayashi Yasuhiro¹^ORCID,Otani Erika¹,Watanabe Hikari²^ORCID,Han Jihae¹^ORCID

Affiliation:

1. Graduate School of Science and Technology, Niigata University, 8050 Ikarashi, 2-no-cho, Nishi-ku, Niigata, 950-2181, Japan

2. Department of Pure and Applied Chemistry, Faculty of Science and Technology, Tokyo University of Science, 2641 Yamazaki, Noda, Chiba 278-8510, Japan

Abstract

Li[(CF3SO2)2N] mixtures with propane sultone or sulfolane, newly termed as glass-forming liquid electrolytes, exhibited large-size aggregate (AGG) formation via speciation and dipole reorientation. The AGGs may be crucial for the unique Li+ conduction.

Funder

Japan Society for the Promotion of Science

Advanced Low Carbon Technology Research and Development Program

Ministry of Education, Culture, Sports, Science and Technology

Japan Science and Technology Agency

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/FD/D4FD00050A

Reference46 articles.

1. Unusual Stability of Acetonitrile-Based Superconcentrated Electrolytes for Fast-Charging Lithium-Ion Batteries

2. Review—Superconcentrated Electrolytes for Lithium Batteries

3. Solvate Ionic Liquids and Their Application to Lithium Batteries: Glyme-Lithium Bis(fluorosulfonyl)amide Equimolar Complexes

4. Glyme–Lithium Salt Equimolar Molten Mixtures: Concentrated Solutions or Solvate Ionic Liquids?

5. From Ionic Liquids to Solvate Ionic Liquids: Challenges and Opportunities for Next Generation Battery Electrolytes