Spin-polarized p-block antimony/bismuth single-atom catalysts on defect-free rutile TiO<sub>2</sub>(110) substrate for highly efficient CO oxidation-Reference-Cited by-同舟云学术

Spin-polarized p-block antimony/bismuth single-atom catalysts on defect-free rutile TiO₂(110) substrate for highly efficient CO oxidation

Published:2024 Issue:23 Volume:26 Page:16459-16465
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Shi Jinlei¹²,Yang Fengyuan²,Zhao Xingju²^ORCID,Ren Xiaoyan²^ORCID,Tang Yanan¹^ORCID,Li Shunfang²^ORCID

Affiliation:

1. College of Physics and Electronic Engineering, Zhengzhou Normal University, Zhengzhou 450044, China

2. School of Physics and Microelectronics, Zhengzhou University, Zhengzhou, Henan 450001, China

Abstract

We establish a new strategy for constructing spin-polarized single Bi/Sb atoms on defect-free TiO2(110), showing excellent catalytic activities for spin-triplet O2 activation and CO oxidation with low rate-limiting reaction barrier of ∼0.6 eV.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CP/D4CP00352G

Reference56 articles.

1. Single-atom catalysis of CO oxidation using Pt1/FeOx

2. Single-Atom Catalysts: A New Frontier in Heterogeneous Catalysis

3. CO Oxidation on Supported Single Pt Atoms: Experimental and ab Initio Density Functional Studies of CO Interaction with Pt Atom on θ-Al2O3(010) Surface

4. CO Oxidation on Aun/TiO2 Catalysts Produced by Size-Selected Cluster Deposition

5. A Mn-N3 single-atom catalyst embedded in graphitic carbon nitride for efficient CO2 electroreduction

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