Homochiral <i>vs.</i> heterochiral preference in chiral self-recognition of cyclic diols-Reference-Cited by-同舟云学术

Homochiral vs. heterochiral preference in chiral self-recognition of cyclic diols

Published:2024 Issue:14 Volume:26 Page:10610-10621
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Dupont Jennifer¹,Hartwig Beppo²^ORCID,Le Barbu-Debus Katia¹^ORCID,Lepere Valeria¹^ORCID,Guillot Regis³^ORCID,Suhm Martin A.²^ORCID,Zehnacker Anne¹^ORCID

Affiliation:

1. Institut des Sciences Moléculaires d’Orsay (ISMO), CNRS, rue André Rivière, Université Paris-Saclay, F-91405 Orsay, France

2. Institut für Physikalische Chemie, Georg-August-Universität Göttingen, Tammannstr. 6, 37077 Göttingen, Germany

3. Institut de Chimie Moléculaire et des Matériaux d’Orsay (ICMMO), 17 Av. des Sciences Université Paris-Saclay, F-91405 Orsay, France

Abstract

Substitution of the transiently chiral cis-1,2-cyclohexanediol (cis-CD) by a phenyl results in (S,S)-(+)-1-phenylcyclohexane-cis-1,2-diol (cis-PCD) and modifies the hydrogen bond pattern in its dimer. The heterochiral preference observed in cis-CD changes for homochiral in cis-PCD.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CP/D4CP00351A

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