Magnesium amino-bis(phenolato) complexes for the ring-opening polymerization of rac-lactide

Author:

Devaine-Pressing Katalin1234,Lehr Joshua H.1234,Pratt Michelle E.1234,Dawe Louise N.12345,Sarjeant Amy A.1678,Kozak Christopher M.1234

Affiliation:

1. Department of Chemistry

2. Memorial University of Newfoundland

3. St. John's

4. Canada A1B 3X7

5. C-CART X-ray Diffraction Laboratory

6. Northwestern University

7. Evanston

8. USA

Abstract

Magnesium complexes capable of rac-lactide polymerization in both the melt and in solution at elevated temperatures were synthesized. End-group analysis by MALDI-TOF showed both linear and cyclic PLA.

Funder

Natural Sciences and Engineering Research Council of Canada

Canada Foundation for Innovation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference70 articles.

1. Marine-degradable polylactic acid

2. J. M. Becker and A. P.Dove, in Green Polymerization Methods: Renewable Starting Materials, Catalysis and Waste Reduction, eds. R. T. Mathers and M. A. R. Meier, Wiley-VCH, Weinheim, 1st edn, 2011, pp. 201–220

3. Polylactic Acid Technology

4. Controlled Ring-Opening Polymerization of Lactide and Glycolide

5. Stereocontrolled ring-opening polymerisation of lactide

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