Investigation of the rhodium-catalyzed hydroboration of NHC-boranes: the role of alkene coordination and the origin of enantioselectivity
Author:
Affiliation:
1. Aix Marseille University
2. CNRS
3. Marseille
4. France
Abstract
The mechanism of the intramolecular enantioselective rhodium(i)-catalyzed hydroboration of NHC-boranes is investigated by experiments and calculations, using Density Functional Theory and Random Phase Approximation methods.
Funder
Aix-Marseille Université
Centre National de la Recherche Scientifique
Agence Nationale de la Recherche
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT03660A
Reference77 articles.
1. A New Powerful Reducing Agent—Sodium Borohydride in the Presence of Aluminum Chloride and Other Polyvalent Metal Halides1,2
2. Amine-Directed Hydroboration: Scope and Limitations
3. Amine− and Phosphine−Borane Adducts: New Interest in Old Molecules
4. Boron- and phosporus-containing heterocycles: First evidence of a transient cyclic phosphaborolane with PH and BH bonds
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