[Au12(PPh2)2S4(L2)4]2+ (L2 = 3,4-bis(diphenylphosphino)-2,5-bis(trimethylsilyloxy)furan): an Au12 unit protected by modified maleic anhydride phosphine ligands-Reference-Cited by-同舟云学术

[Au12(PPh2)2S4(L2)4]2+ (L2 = 3,4-bis(diphenylphosphino)-2,5-bis(trimethylsilyloxy)furan): an Au12 unit protected by modified maleic anhydride phosphine ligands

Published:2018 Issue:4 Volume:47 Page:1032-1035
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Yu Wen¹²³⁴⁵,Wang Yingxia⁶⁷⁸⁹¹⁰,Fuhr Olaf⁶⁷⁸⁹¹⁰^ORCID,Fenske Dieter¹¹⁷¹²⁹⁶,Dehnen Stefanie⁵¹³¹⁴⁹^ORCID

Affiliation:

1. Zhejiang University of Science and Technology

2. School of Biological and Chemical Engineering

3. 310023 Hangzhou

4. China

5. Fachbereich Chemie and Wissenschaftliches Zentrum für Materialwissenschaften (WZMW)

6. Institut für Nanotechnologie (INT) und Karlsruher Nano-Micro-Facility (KNMF)

7. Karlsruher Institut für Technologie (KIT)

8. 76344 Eggenstein-Leopoldshafen

9. Germany

10. Lehn Institute of Functional Materials (LIFM)

11. Institut für Anorganische Chemie

12. 76131 Karlsruhe

13. Philipps-Universität Marburg

14. 35043 Marburg

Abstract

The reaction of the bis(dichlorogold) complex of 2,3-bis(diphenylphosphino)maleic anhydride (L1) with S(SiMe₃)₂ in the presence of NaBPh₄ yields the ionic dodecanuclear cluster compound [Au₁₂(PPh₂)₂S₄(L2)₄](BPh₄)₂ (1).

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C7DT04263A

Reference42 articles.

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4. The Intrinsic3[dσ*pσ] Emission of Binuclear Gold(I) Complexes with Two Bridging Diphosphane Ligands Lies in the Near UV; Emissions in the Visible Region Are Due to Exciplexes

5. A Highly Soluble Luminescent Decanuclear Gold(I) Complex with a Propeller-Shaped Structure

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