The vibronic state dependent predissociation of H2S: determination of all fragmentation processes

Author:

Zhao Yarui12,Chen Junjie3,Luo Zijie2,Chang Yao2ORCID,Yang Jiayue2,Zhang Weiqing2,Wu Guorong2ORCID,Crane Stuart W.4ORCID,Hansen Christopher S.5ORCID,Ding Hongbin1ORCID,An Feng3,Hu Xixi67ORCID,Xie Daiqian37ORCID,Ashfold Michael N. R.4ORCID,Yuan Kaijun27ORCID,Yang Xueming278ORCID

Affiliation:

1. School of Physics, Key Laboratory of Materials Modification by Laser, Ion and Electron Beams, Chinese Ministry of Education, Dalian University of Technology, Dalian, 116024, China

2. State Key Laboratory of Molecular Reaction Dynamics and Dalian Coherent Light Source, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China

3. Institute of Theoretical and Computational Chemistry, Key Laboratory of Mesoscopic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

4. School of Chemistry, University of Bristol, Bristol, BS8 1TS, UK

5. School of Chemistry, University of New South Wales, Sydney, NSW 2052, Australia

6. Kuang Yaming Honors School, Institute for Brain Sciences, Jiangsu Key Laboratory of Vehicle Emissions Control, Center of Modern Analysis, Nanjing University, Nanjing 210023, China

7. Hefei National Laboratory, Hefei 230088, China

8. Department of Chemistry, Southern University of Science and Technology, Shenzhen 518055, China

Abstract

The comprehensive picture of the fragmentation behaviour of H2S has been provided by detecting the H, S(1D) and S(1S) atom products at wavelengths 155–120 nm.

Funder

National Natural Science Foundation of China

Chinese Academy of Sciences

Liaoning Revitalization Talents Program

Australian Research Council

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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