Self-assembled mesoscopic surface domains of fluorocarbon–hydrocarbon diblocks can form at zero surface pressure: tilting of solid-like hydrocarbon moieties compensates for cross-section mismatch with fluorocarbon moieties
Author:
Affiliation:
1. Institute of Chemistry
2. Martin-Luther University Halle-Wittenberg
3. D-06099 Halle (Saale)
4. Germany
5. Institut Charles Sadron (CNRS)
6. University of Strasbourg
7. F-67034 Strasbourg
8. France
Abstract
Surface domains of C8F17C16H33 exist at zero surface pressure with solid-like alkyl chains stretched in an all-trans configuration, shown using IRRAS.
Funder
Agence Nationale de la Recherche
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2017/CP/C7CP02432K
Reference48 articles.
1. Chemistry, Physical Chemistry, and Uses of Molecular Fluorocarbon−Hydrocarbon Diblocks, Triblocks, and Related Compounds—Unique “Apolar” Components for Self-Assembled Colloid and Interface Engineering
2. Large Organized Surface Domains Self-Assembled from Nonpolar Amphiphiles
3. Surface activity of semifluorinated alkanes: F(CF2)m(CH2)nH
4. Surface Crystallization and Phase Transitions of the Adsorbed Film of F(CF2)12(CH2)16H at the Surface of Liquid Hexadecane
5. Aggregates from semifluorinated n-alkanes: how incompatibility determines self-assembly
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