Methanol oxidation on Ru(0001) for direct methanol fuel cells: analysis of the competitive reaction mechanism
Author:
Affiliation:
1. College of Science
2. China University of Petroleum
3. Qingdao
4. P. R. China
5. Department of Physics and Materials Science
6. City University of Hong Kong
Abstract
Competitive oxidation of CH3OH to CH2O occur via CH3OH → CH3O → CH2O vs. CH3OH → CH2OH → CH2O, further to COOH by the OH group via CH2O → CHO → CO + OH → COOH vs. CH2O + OH → CH2OOH → CHOOH → COOH, and finally oxidation to CO2 on Ru(0001).
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/RA/C5RA21793H
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