Unexpected effect of catalyst concentration on photochemical CO2 reduction by trans(Cl)–Ru(bpy)(CO)2Cl2: new mechanistic insight into the CO/HCOO− selectivity
Author:
Affiliation:
1. Department of Chemistry
2. Graduate School of Science
3. Kitasato University
4. Sagamihara
5. Japan
Abstract
We found catalyst concentration dependence of the product ratio in the photochemical reduction of CO2, and proposed a new mechanism involving a Ru(i)–Ru(i) dimer intermediate.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC00199D
Reference86 articles.
1. Anthropogenic Chemical Carbon Cycle for a Sustainable Future
2. Solar Energy Supply and Storage for the Legacy and Nonlegacy Worlds
3. Chemical Approaches to Artificial Photosynthesis. 2
4. Catalysis Research of Relevance to Carbon Management: Progress, Challenges, and Opportunities
5. Approach to multi-electron reduction beyond two-electron reduction of CO2
Cited by 104 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
1. Mechanism of photocatalytic CO2 reduction to HCO2H by a robust multifunctional iridium complex;Dalton Transactions;2024
2. Overall reaction mechanism of photocatalytic CO2 reduction on a Re(i)-complex catalyst unit of a Ru(ii)–Re(i) supramolecular photocatalyst;Chemical Science;2024
3. Synthesis of Polyethylenes with In-Chain Isolated Carbonyls from CO 2 and Ethylene via a Tandem Photoreduction/Polymerization Protocol;CCS Chemistry;2023-10-26
4. Chitosan-Comodified Surface-Grafted Thermosensitive Ion-Imprinted Composite Membrane for the Selective Recognition and Separation of ReO4–;ACS Applied Polymer Materials;2023-08-03
5. Polymeric Unimolecular CO Dehydrogenase Mimic with both Inner and Outer Spheres for Enhanced Photocatalytic CO2 Reduction in Aqueous Solution;Chemistry – A European Journal;2023-05-19
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3