Padlocking dihydrofurannulation for the control of small degree of helicity built on a fused-tetracyclic core-Reference-Cited by-同舟云学术

Padlocking dihydrofurannulation for the control of small degree of helicity built on a fused-tetracyclic core

Published:2024 Issue:19 Volume:15 Page:7300-7307
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Gaucherand Arthur¹^ORCID,Yen-Pon Expédite¹,García-López Diego¹,Naubron Jean-Valère²,Chentouf Sara²,Giorgi Michel²^ORCID,Humbel Stéphane¹^ORCID,Jean Marion¹,Rodriguez Jean¹,Bonne Damien¹^ORCID

Affiliation:

1. Aix Marseille Université, CNRS, Centrale Marseille, iSm2, Marseille, France

2. Aix Marseille Université, CNRS, Centrale Marseille, FSCM, Spectropole, Marseille, France

Abstract

An organocatalyzed enantioselective domino reaction has been developed for the synthesis of configurationally locked helically chiral fused tetracyclic cores. This methodology allows the modulation of the helicity in the final molecule.

Funder

Agence Nationale de la Recherche

Centre National de la Recherche Scientifique

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC00745J

Reference33 articles.

1. The Challenge of Atropisomerism in Drug Discovery

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5. Structurally Diverse Second-Generation [2.2]Paracyclophane Ketimines with Planar and Central Chirality: Syntheses, Structural Determination, and Evaluation for Asymmetric Catalysis

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