Rotational isomerism of the amide units in rotaxanes based on a cyclic tetraamide and secondary ammonium ions

Author:

Okuma Yukari12345,Tsukamoto Toshihiro12345,Inagaki Takayuki12345,Miyagawa Shinobu12345,Kimura Masaki12345,Naito Masaya12345ORCID,Takaya Hikaru67895ORCID,Kawasaki Tsuneomi1011125ORCID,Tokunaga Yuji12345ORCID

Affiliation:

1. Department of Materials Science and Engineering

2. Faculty of Engineering

3. University of Fukui

4. Fukui 910-8507

5. Japan

6. International Research Center for Elements Science

7. Institute for Chemical Research

8. Kyoto University

9. Uji 611-0011

10. Department of Applied Chemistry

11. Tokyo University of Science

12. Tokyo 162-8601

Abstract

We describe the synthesis of [2]rotaxanes consisting of a macrocyclic tetraamide and mono- and bis-ammonium ions and their conformational isomerism.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

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