Trapping of soluble, KCl-stabilized Cu(<scp>i</scp>) hydrides with CO<sub>2</sub> gives crystalline formates-Reference-Cited by-同舟云学术

Trapping of soluble, KCl-stabilized Cu(i) hydrides with CO₂ gives crystalline formates

Published:2023 Issue:93 Volume:59 Page:13879-13882
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Grasruck Alexander¹,Parla Giorgio¹,Lou Lisha¹,Langer Jens¹^ORCID,Neiß Christian²^ORCID,Herrera Alberto¹,Frieß Sybille¹,Görling Andreas²^ORCID,Schmid Günter³^ORCID,Dorta Romano¹^ORCID

Affiliation:

1. Department Chemie und Pharmazie, Anorganische und Allgemeine Chemie, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstraße 1, 91058 Erlangen, Germany

2. Department Chemie und Pharmazie, Theoretische Chemie, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstraße 3, 91058 Erlangen, Germany

3. Siemens Energy Global GmbH & Co. KG, New Energy Business – Technology & Products, Freyeslebenstraße 1, 91058 Erlangen, Germany

Abstract

Cu(i)-Hydrido complexes supported by dibenzo[b,f]azepinyl P-alkene hybrid ligands and stabilized by electrostatic interactions in a Cu–H⋯KCl⋯BR3 arrangement can be trapped with CO2 at low temperature to afford Cu(i)-formates.

Funder

Bundesministerium für Bildung und Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC03033D

Reference39 articles.

1. CuH-Catalyzed Reactions

2. CuH-Catalyzed Olefin Functionalization: From Hydroamination to Carbonyl Addition

3. Coinage Metal Hydrides: Synthesis, Characterization, and Reactivity

4. Reactivity of Copper Electrodes towards Functional Groups and Small Molecules in the Context of CO2 Electro-Reductions

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1. Lewis Acid‐Tethered (cAAC)—Copper Complexes: Reactivity for Hydride Transfer and Catalytic CO₂ Hydrogenation;Angewandte Chemie;2024-09-05

2. Lewis Acid‐Tethered (cAAC)—Copper Complexes: Reactivity for Hydride Transfer and Catalytic CO₂ Hydrogenation;Angewandte Chemie International Edition;2024-09-05

3. Dibenzoazepine hydrazine is a building block for N-alkene hybrid ligands: exploratory syntheses of complexes of Cu, Fe, and Li;Dalton Transactions;2024