Lead-free iron-doped Cs3Bi2Br9 perovskite with tunable properties

Author:

Htun Thiri1,Elattar Amr23,Elbohy Hytham4ORCID,Tsutsumi Kosei1,Horigane Kazumasa5,Nakano Chiyu6,Gu Xiaoyu7,Suzuki Hiroo1,Nishikawa Takeshi1,Kyaw Aung Ko Ko7ORCID,Hayashi Yasuhiko1

Affiliation:

1. Graduate School of Natural Science and Technology, Okayama University, Japan

2. Department of Chemistry, Faculty of Science, Ain Shams University, Cairo, Egypt

3. Industrial & Manufacturing Engineering, FAMU-FSU College of Engineering, 2525 Pottsdamer St, Tallahassee, Florida, 32310, USA

4. Physics Department, Faculty of Science, Damietta University, Egypt

5. Research Institute for Interdisciplinary Science, Okayama University, Japan

6. Advanced Science Research Center, Okayama University, Okayama, Japan

7. Guangdong University Key Laboratory for Advanced Quantum Dot Displays and Lighting and Department of Electronic & Electrical Engineering, Southern University of Science and Technology, P. R. China

Abstract

The bandgap of lead-free, non-toxic Cs3Bi2Br9 perovskite material is reduced from 2.54 eV to 1.78 eV by changing the crystal structure to Cs3Bi2−xFexBr9, Cs2Bi1−xFexBr5, and CsFeBr4, depending on the varying Fe doping concentrations.

Funder

Ministry of Education, Culture, Sports, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

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