Thermally controlled growth of photoactive FAPbI3 films for highly stable perovskite solar cells

Author:

Sánchez Sandy12ORCID,Cacovich Stefania3ORCID,Vidon Guillaume4ORCID,Guillemoles Jean-François3,Eickemeyer Felix1,Zakeeruddin Shaik M.1,Schawe Jürgen E. K.56ORCID,Löffler Jörg F.5ORCID,Cayron Cyril7,Schouwink Pascal8,Graetzel Michael1

Affiliation:

1. Laboratory of Photonics and Interfaces, Institute of Chemistry and Chemical Engineering, École Polytechnique Fédérale de Lausanne, 1015 Lausanne, Switzerland

2. Laboratory for Molecular Engineering of Optoelectronic Nanomaterials, Institute of Chemistry and Chemical Engineering, École Polytechnique Fédérale de Lausanne, 1015 Lausanne, Switzerland

3. CNRS, Institut Photovoltaïque d’Île de France (IPVF), UMR 9006, 18 boulevard Thomas Gobert, 91120 Palaiseau, France

4. IPVF, 18, boulevard Thomas Gobert, 91120 Palaiseau, France

5. Laboratory of Metal Physics and Technology, Department of Materials, ETH Zurich, 8093 Zurich, Switzerland

6. Mettler-Toledo GmbH, Analytical, 8606 Nänikon, Switzerland

7. Laboratory of Thermomechanical Metallurgy (LMTM), PX Group Chair, Ecole Polytechnique Fédérale de Lausanne (EPFL), Rue de la Maladière 71b, 2022 Neuchâtel, Switzerland

8. Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne (EPFL), 1950 Sion, Switzerland

Abstract

In this work, we elucidate the relationship between heating-rate and FAPbI3 perovskite phase transformation, bringing a new relationship with crystal growth parameters. Thus, we manufactured highly stable perovskite solar cells with a 640 ms IR pulse.

Funder

H2020 Marie Skłodowska-Curie Actions

Horizon 2020 Framework Programme

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

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