Chromium-catalyzed migratory arylmagnesiation of unactivated alkynes

Author:

Yan Jianming1234,Yoshikai Naohiko1234ORCID

Affiliation:

1. Division of Chemistry and Biological Chemistry

2. School of Physical and Mathematical Sciences

3. Nanyang Technological University

4. Singapore

Abstract

The first example of 1,4-chromium migration was observed in the addition of an aryl Grignard reagent to an unactivated alkyne.

Funder

Ministry of Education - Singapore

Nanyang Technological University

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Reference42 articles.

1. Recent advances in transition-metal-catalyzed intermolecular carbomagnesiation and carbozincation

2. Recent Advances in Efficient and Selective Synthesis of Di-, Tri-, and Tetrasubstituted Alkenes via Pd-Catalyzed Alkenylation−Carbonyl Olefination Synergy

3. Stereocontrolled Synthesis of Tetrasubstituted Olefins

4. I. Marek , N.Chinkov and D.Banon-Tenne, in Metal-Catalyzed Cross-Coupling Reactions, ed. A. de Meijere and F. Diederich, Wiley-VCH, Weinheim, 2004, pp. 395–478

5. P. Knochel , in Comprehensive Organic Synthesis, ed. B. M. Trost, I. Fleming and M. F. Semmelhack, Pergamon Press, New York, 1991, pp. 865–911

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