Kinetic trapping of a cobalt(ii) metallocage using a carbazole-containing expanded carbaporphyrinoid ligand-Reference-Cited by-同舟云学术

Kinetic trapping of a cobalt(ii) metallocage using a carbazole-containing expanded carbaporphyrinoid ligand

Published:2022 Issue:3 Volume:13 Page:692-697
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Zhou Weinan¹²,Sarma Tridib³^ORCID,Su Yonghuan²,Lei Chuanhu²^ORCID,Sessler Jonathan L.⁴^ORCID

Affiliation:

1. School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China

2. Center for Supramolecular Chemistry and Catalysis and Department of Chemistry, College of Science, Shanghai University, Shanghai 200444, China

3. Department of Chemistry, Cotton University, Guwahati 781001, Assam, India

4. Department of Chemistry, The University of Texas at Austin, 105 East 24th Street, Stop A5300, Austin, Texas 78712-1224, USA

Abstract

Carbazole containing expanded carbaporphyrinoid ligand supports the formation of 2 : 1 metal-to-ligand complexes with Pd, Co, and Zn. Solid-state studies also revealed formation of a 6 : 3 metal-to-ligand metallocage in the case of Co complexation.

Funder

Shanghai University

National Natural Science Foundation of China

Welch Foundation

Shanghai Rising-Star Program

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D1SC06514A

Reference42 articles.

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4. Metalation of Expanded Porphyrins: A Chemical Trigger Used To Produce Molecular Twisting and Möbius Aromaticity

5. PdIIComplexes of [44]- and [46]Decaphyrins: The Largest Hückel Aromatic and Antiaromatic, and Möbius Aromatic Macrocycles

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