Oxidation of methanol to methyl formate over supported Pd nanoparticles: insights into the reaction mechanism at low temperature
Author:
Affiliation:
1. Institute of Condensed Matter and Nanosciences (IMCN)
2. Université catholique de Louvain
3. Division Molecules
4. Solids and Reactivity (MOST)
5. 1348 Louvain la Neuve, Belgium
Abstract
The mechanism of methyl formate formation at low temperature was studied using DRIFT-operando. The first reaction step would be the formation of methoxy groups by dissociative adsorption of methanol and then transformation into formaldehyde. The final step would be the condensation of the formaldehyde species with gaseous methanol.
Publisher
Royal Society of Chemistry (RSC)
Subject
Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2014/CY/C4CY00531G
Reference27 articles.
1. Porous Palladium Nanoflowers that Have Enhanced Methanol Electro-Oxidation Activity
2. Direct Methyl Formate Formation from Methanol over Supported Palladium Nanoparticles at Low Temperature
3. Influence of the Preparation Method on Catalytic Properties of Pd/TiO2 Catalysts in the Reaction of Partial Oxidation of Methanol
4. Low temperature oxidation of methanol to methyl formate over Pd nanoparticles supported on γ-Fe2O3
5. Hybrid Cu–ZnO–ZrO2/H-ZSM5 system for the direct synthesis of DME by CO2 hydrogenation
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