Thiol–yne chemistry of diferrocenylacetylene: from synthesis and electrochemistry to theoretical studies-Reference-Cited by-同舟云学术

Thiol–yne chemistry of diferrocenylacetylene: from synthesis and electrochemistry to theoretical studies

Published:2022 Issue:40 Volume:51 Page:15412-15424
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bruña Sonia¹²^ORCID,Valverde-González Antonio¹^ORCID,Montero-Campillo M. Merced³^ORCID,Mó Otilia²³^ORCID,Cuadrado Isabel¹²^ORCID

Affiliation:

1. Departamento de Química Inorgánica, Facultad de Ciencias, Calle Francisco Tomás y Valiente, 7, Universidad Autónoma de Madrid, Ciudad Universitaria de Cantoblanco, 28049, Madrid, Spain

2. Institute for Advanced Research in Chemical Sciences (IAdChem), Facultad de Ciencias, Calle Francisco Tomás y Valiente, 7, Universidad Autónoma de Madrid, Ciudad Universitaria de Cantoblanco, 28049, Madrid, Spain

3. Departamento de Química, Facultad de Ciencias, Calle Francisco Tomás y Valiente, 7, Universidad Autónoma de Madrid, Ciudad Universitaria de Cantoblanco, 28049, Madrid, Spain

Abstract

The first thiol–yne coupling reactions of diferrocenylacetylene, which presents an internal CC bond and two ferrocenes, are investigated. The obtained vinyl thioether sulfide isomers have been isolated and show an interesting redox behavior.

Funder

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT02378D

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