An α-diiminato germylene family: syntheses, structures, and reactivity towards C–C coupled digermylene and digermylene oxide-Reference-Cited by-同舟云学术

An α-diiminato germylene family: syntheses, structures, and reactivity towards C–C coupled digermylene and digermylene oxide

Published:2022 Issue:22 Volume:51 Page:8671-8679
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Liu Jingjing¹,Shang Jianxuan²,Wei Jing¹,Gao Fangfang¹,Hou Lei¹^ORCID,Zeng Fanlong¹^ORCID,Li Anyang¹^ORCID,Wang Wenyuan¹^ORCID

Affiliation:

1. Key Laboratory of Synthetic and Natural Functional Molecule of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an 710127, P. R. China

2. Shaanxi Coal and Chemical Industry, Xi'an 710054, P. R. China

Abstract

The synthesis and reactivity of a germylene chloride 2 stabilized by a rigid α-diiminate ligand was systematically explored to afford a new family of germylenes, which bonding nature was revealed by their XRD structures and DFT calculations.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT00981A

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