Reductive elimination of [AlH2]+ from a cationic Ga–Al dihydride-Reference-Cited by-同舟云学术

Reductive elimination of [AlH2]+ from a cationic Ga–Al dihydride

Published:2021 Issue:74 Volume:57 Page:9454-9457
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Morris Louis J.¹^ORCID,Carpentier Ambre²,Maron Laurent²^ORCID,Okuda Jun¹^ORCID

Affiliation:

1. Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, 52056 Aachen, Germany

2. CNRS, INSA, UPS, UMR 5215, LPCNO, Université de Toulouse, 135 avenue de Rangueil, 31077 Toulouse, France

Abstract

A heterobimetallic dihydride cation with a covalent Al–Ga bond forms by formal oxidative addition of [AlH2]+ to Ga(i). The reverse reaction is initiated by coordination of THF or NHC, but does not occur for the Al–Al bonded homobimetallic analogue.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC03706D

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3. Crystal structure of tetramethylammonium hexachlorodigallate(II)

4. Neutral complexes of gallium di-iodide containing Ga—Ga bonds

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