Dominance of unique P⋯π phosphorus bonding with π donors: evidence using matrix isolation infrared spectroscopy and computational methodology
Author:
Affiliation:
1. Homi Bhabha National Institute
2. Materials Chemistry & Metal Fuel Cycle Group
3. Indira Gandhi Center for Atomic Research
4. Kalpakkam – 603102
5. India
Abstract
The preferential generation and directional determinism of P⋯π phosphorus bonding within low temperature matrices has been established as a consequence of electrostatic dominance in stabilization.
Funder
Department of Atomic Energy, Government of India
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP02880K
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