Electron-deficient copper pnictides: A2Mg3Cu9Pn7 (A = Sr, Eu; Pn = P, As) and Eu5Mg2.39Cu16.61As12-Reference-Cited by-同舟云学术

Electron-deficient copper pnictides: A2Mg3Cu9Pn7 (A = Sr, Eu; Pn = P, As) and Eu5Mg2.39Cu16.61As12

Published:2016 Issue:10 Volume:3 Page:1264-1271
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Zhu Min¹²³⁴⁵,Tao Xu-Tang¹²³⁴⁵,Xia Sheng-Qing¹²³⁴⁵

Affiliation:

1. State Key Laboratory of Crystal Materials

2. Institute of Crystal Materials

3. Shandong University

4. Jinan

5. People's Republic of China

Abstract

Five pnictide Zintl compounds, A₂Mg₃Cu₉Pn₇ (A = Sr, Eu; Pn = P, As) and Eu₅Mg_2.39Cu_16.61As₁₂, were synthesized from the Pb-flux reactions. The anion structures of these compounds can be described as being composed of edge- or corner-sharing CuPn₄ tetrahedra, which construct complex 3D frameworks with cations filled into the cavities.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/QI/C6QI00221H

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