A long-lived fluorenyl cation: efficiency booster for uncaging and photobase properties-Reference-Cited by-同舟云学术

A long-lived fluorenyl cation: efficiency booster for uncaging and photobase properties

Published:2022 Issue:9 Volume:24 Page:5294-5300
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Abdellaoui Chahinez¹,Hermanns Volker²,Reinfelds Matiss²³^ORCID,Scheurer Maximilian⁴^ORCID,Dreuw Andreas⁴^ORCID,Heckel Alexander²^ORCID,Wachtveitl Josef¹^ORCID

Affiliation:

1. Institute of Physical and Theoretical Chemistry, Goethe-University Frankfurt, Frankfurt am Main 60438, Germany

2. Institute of Organic Chemistry, Goethe-University Frankfurt, Frankfurt am Main 60438, Germany

3. Institute of Chemistry and Technology of Materials (ICTM), NAWI Graz, Graz University of Technology, Graz 8010, Austria

4. Interdisciplinary Center for Scientific Computing, Heidelberg University, Heidelberg 69120, Germany

Abstract

The symmetric dimethylamino-fluorene proved to be a more efficient photolabile protecting group than non-symmetric analogue. This is due to the long-lived fluorenyl cation intermediate, which also enables application as hydroxide emitting photobase.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D1CP05292F

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3. A Benzophenone‐Based Photocaging Strategy for the N7 Position of Guanosine

4. Light-triggered elimination of CO2 and absorption of O2 (artificial breathing reaction) in photolysis of 2-(4-nitrophenyl)-1H-indole derivatives

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