Reductive linear- and cyclo-trimerization of isocyanides using an Al–Al-bonded compound-Reference-Cited by-同舟云学术

Reductive linear- and cyclo-trimerization of isocyanides using an Al–Al-bonded compound

Published:2019 Issue:64 Volume:55 Page:9452-9455
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Chen Weixing¹²³⁴⁵,Zhao Yanxia¹²³⁴⁵^ORCID,Xu Wenhua¹²³⁴⁵,Su Ji-Hu⁶⁷⁸⁹⁵,Shen Lingyi¹²³⁴⁵,Liu Li¹²³⁴⁵,Wu Biao¹²³⁴⁵^ORCID,Yang Xiao-Juan¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education

2. College of Chemistry and Materials Science

3. Northwest University

4. Xi’an 710069

5. China

6. Hefei National Laboratory for Physical Sciences at the Microscale and Department of Modern Physics

7. CAS Key Laboratory of Microscale Magnetic Resonance

8. University of Science and Technology of China

9. Hefei 230026

Abstract

Dialumane can promote cyclo-trimerization of isocyanides in the presence of Na, affording the product [Na][LAl{μ-η¹:η²-(tBuNC)₃}Al(CN)L] with a unique aromatic tri(tert-butylimino)deltate dianion [C₃N₃(tBu)₃]²⁻.

Funder

National Natural Science Foundation of China

China Postdoctoral Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C9CC04344F

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5. Twofold Insertion of Isocyanides into the GaGa Bond of Tetrakis[bis(trimethylsilyl)methyl]digallane(4)

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