Why can Dispolreg 007 control the nitroxide mediated polymerization of methacrylates?
Author:
Affiliation:
1. POLYMAT and Kimika Aplikatua Saila
2. University of the Basque Country UPV/EHU
3. Joxe Mari Korta Zentroa
4. Donostia/San Sebastián
5. Spain
Abstract
The alkoxyamine 3-(((2-cyanopropan-2-yl)oxy)(cyclohexyl)amino)-2,2-dimethyl-3-phenylpropanenitrile (Dispolreg 007) has recently emerged as a robust regulator for the controlled (co)polymerization of methacrylates and styrene by nitroxide mediated polymerization.
Funder
Euskal Herriko Unibertsitatea
Eusko Jaurlaritza
Ministerio de Economía y Competitividad
Ministerio de Ciencia e Innovación
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering
Link
http://pubs.rsc.org/en/content/articlepdf/2019/PY/C8PY00900G
Reference57 articles.
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4. Synthesis and Characterization of ω-Unsaturated Poly(styrene-b-n-butyl methacrylate) Block Copolymers Using TEMPO-Mediated Controlled Radical Polymerization
5. Intramolecular proton transfer (IPT) in alkoxyamine: a theoretical investigation
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