Nickel(iii)-mediated oxidative cascades from a thiol-bearing nickel(ii) precursor to the nickel(iv) product-Reference-Cited by-同舟云学术

Nickel(iii)-mediated oxidative cascades from a thiol-bearing nickel(ii) precursor to the nickel(iv) product

Published:2018 Issue:11 Volume:47 Page:3796-3802
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Chang Hao-Ching¹²³⁴^ORCID,Lin Sheng-Hsiang¹²³⁴^ORCID,Hsu Yu-Chen¹²³⁴,Jen Shao-Wei¹²³⁴,Lee Way-Zen¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. National Taiwan Normal University

3. Taipei 11677

4. Republic of China

Abstract

Triggered by deprotonation, a nickel(ii) complex, Ni(HPS2)₂ (1) that contains two pendant thiols, is rapidly aerobically oxidized to a diamagnetic nickel(iv) complex, Ni(PS2)₂ (2), through EPR-active nickel(iii) intermediates.

Funder

Ministry of Science and Technology, Taiwan

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C7DT04137C

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