Aerial carbon dioxide conversion to carbonate mediated by a lead(ii) complex with tridentate bipyridine containing a hydrazide ligand under electrochemical conditions yielding single-component white-light-emitting phosphors

Author:

Mahmoudi Ghodrat123ORCID,Garcia-Santos Isabel4ORCID,Labisbal Elena4,Castiñeiras Alfonso4ORCID,Alizadeh Vali5,Gomila Rosa M.6ORCID,Frontera Antonio6ORCID,Safin Damir A.78ORCID

Affiliation:

1. Department of Chemistry, Faculty of Science, University of Maragheh, P.O. Box 55136-83111, Maragheh, Iran

2. Chemistry Department, Faculty of Engineering and Natural Sciences, Istinye University, Sarıyer, Istanbul 34396, Turkey

3. Western Caspian University, Istiqlaliyyat Street 31, AZ 1001, Baku, Azerbaijan

4. Departamento de Química Inorgánica, Facultad de Farmacia, Universidad de Santiago de Compostela, E-15782 Santiago de Compostela, Spain

5. Department of Petroleum Engineering, Faculty of Engineering, University of Garmsar, Garmsar, Iran

6. Departament de Quimica, Universitat de les Illes Balears, Crta de valldemossa km 7.5, 07122 Palma de Mallorca, Baleares, Spain

7. University of Tyumen, Tyumen, 625003, Russian Federation

8. Scientific and Educational and Innovation Center for Chemical and Pharmaceutical Technologies, Ural Federal University named after the First President of Russia B.N. Yeltsin, Ekaterinburg, 620002, Russian Federation

Abstract

A novel tetranuclear complex [Pb4L4(CO3)2]·4H2O (1·4H2O) is reported, which is obtained through electrochemical oxidation of a lead anode under an ambient atmosphere in a CH3CN : MeOH solution.

Funder

Russian Science Foundation

Federación Española de Enfermedades Raras

Publisher

Royal Society of Chemistry (RSC)

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