Indene formation upon borane-induced cyclization of arylallenes, 1,1-carboboration, and retro-hydroboration-Reference-Cited by-同舟云学术

Indene formation upon borane-induced cyclization of arylallenes, 1,1-carboboration, and retro-hydroboration

Published:2021 Issue: Volume: Page:
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Hasenbeck Max¹²³⁴⁵,Wech Felix¹²³⁴⁵,Averdunk Arthur¹²³⁴⁵,Becker Jonathan⁶²³⁷⁵,Gellrich Urs¹²³⁴⁵^ORCID

Affiliation:

1. Institut für Organische Chemie

2. Justus-Liebig-Universität Gießen

3. Heinrich-Buff-Ring 17

4. 35392 Gießen

5. Germany

6. Institut für Analytische und Anorganische Chemie

7. Gießen 35392

Abstract

The formation of pentafluorophenyl indenes upon reaction of arylallenes with B(C₆F₅)₃ is reported. Key steps are a 1,1-carboboration and a retrohydroboration.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC01750K

Reference33 articles.

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2. 1,1-Carboboration of 1-Alkynes: A Conceptual Alternative to the Hydroboration Reaction

3. Reaction of Frustrated Lewis Pairs with Conjugated Ynones-Selective Hydrogenation of the Carbon-Carbon Triple Bond

4. Frustrated Lewis Pair Reactions With Bis-Acetylenic Substrates: Exploring the Narrow Gap Separating Very Different Competing Reaction Pathways

5. Remarkably variable reaction modes of frustrated Lewis pairs with non-conjugated terminal diacetylenes

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1. Mechanism of Borane‐Catalyzed Oligomerization of Arylallenes and Arylacetylenes;European Journal of Organic Chemistry;2023-12-14

2. Bis(pentafluorophenyl)borane Induced Tandem Hydroboration‐Carboboration of Cyclooctatetraene;Zeitschrift für anorganische und allgemeine Chemie;2023-02

3. Formal [4 + 1] cycloadditions of ketiminoboranes and isonitriles;Organic Chemistry Frontiers;2023

4. Bis(pentafluorophenyl)borane-catalyzed E-selective isomerization of terminal alkenes to internal alkenes;Organic Chemistry Frontiers;2023

5. Piers’ Borane-Catalyzed Dimerization of Arylallenes via Transborylation: A Synthetic and Mechanistic Study;ACS Catalysis;2022-10-31