Slow magnetic relaxation in dinuclear Co(<scp>iii</scp>)–Co(<scp>ii</scp>) complexes containing a five-coordinated Co(<scp>ii</scp>) centre with easy-axis anisotropy-Reference-Cited by-同舟云学术

Slow magnetic relaxation in dinuclear Co(iii)–Co(ii) complexes containing a five-coordinated Co(ii) centre with easy-axis anisotropy

Published:2022 Issue:21 Volume:51 Page:8382-8389
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Liu Mengyao¹,Yang Yimou¹,Jing Rong¹,Zheng Shaojun¹,Yuan Aihua¹^ORCID,Wang Zhenxing²^ORCID,Luo Shu-Chang³^ORCID,Liu Xiangyu⁴^ORCID,Cui Hui-Hui⁵,Ouyang Zhong-Wen²,Chen Lei¹^ORCID

Affiliation:

1. School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, P. R. China

2. Wuhan National High Magnetic Field Center & School of Physics, Huazhong University of Science and Technology, Wuhan 430074, P. R. China

3. School of Chemical Engineering, Guizhou University of Engineering Science, Bijie 551700, P. R. China

4. State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering, National Demonstration Center for Experimental Chemistry Education, College of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021, P. R. China

5. School of Chemistry and Chemical Engineering, Nantong University, Nantong 226019, P. R. China

Abstract

Synthesis, structure, magnetic anisotropy and slow magnetic relaxation of two air-stable Co(iii)–Co(ii) mixed-valence complexes with a five-coordinated Co(ii) centre were studied by single-crystal X-ray crystallography, magnetometry and HFEPR.

Funder

Department of Education of Guizhou Province

Six Talent Peaks Project in Jiangsu Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT00857B

Reference112 articles.

1. Magnetic bistability in a metal-ion cluster