Total synthesis of (−)-akaol A via a conformational constraint strategy-Reference-Cited by-同舟云学术

Total synthesis of (−)-akaol A via a conformational constraint strategy

Published:2018 Issue:12 Volume:5 Page:1886-1889
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Liu Hao-Miao¹²³⁴⁵,Chen Dong¹²³⁴⁵,Xu Wen-Dan¹²³⁴⁵,Dang Li-Zhi⁶⁷⁸⁹,Qin Hong-Bo¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Photochemistry and Plant Resources in West China

2. Kunming Institute of Botany

3. Chinese Academy of Sciences

4. and Yunnan Key laboratory of Natural Medicinal Chemistry

5. Kunming 650201

6. China Tobacco Yunnan Industrial Co.

7. Ltd.

8. Kunming

9. P. R. China

Abstract

Our synthesis of akaol A features a well-designed Friedel–Crafts cyclization, which ensures a cis-fused B/C ring through a conformational constraint strategy.

Funder

National Natural Science Foundation of China

Yunnan Provincial Science and Technology Department

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/QO/C8QO00375K

Reference27 articles.

1. The Dasyscyphins A˜C and Niveulone, New Biologically Active Compounds from the Ascomycete Dasyscyphus niveus

2. Cytotoxic terpenoids from Dasyscyphus niveus

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4. New Sesquiterpene Quinols from a Micronesian Sponge, Aka sp.

5. Synthesis of SHIP1-Activating Analogs of the Sponge Meroterpenoid Pelorol

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