Synthesis of N-aryl β-amino acid derivatives via Cu(ii)-catalyzed asymmetric 1,4-reduction in air-Reference-Cited by-同舟云学术

Synthesis of N-aryl β-amino acid derivatives via Cu(ii)-catalyzed asymmetric 1,4-reduction in air

Published:2019 Issue:16 Volume:9 Page:9187-9192
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Li Min¹²³⁴⁵,Xia Hong-Feng¹²³⁴,Yang Li-Yao¹²³⁴,Hong Tao¹²³⁴,Xie Lin-Jie¹²³⁴,Li Shijun¹²³⁴^ORCID,Wu Jing¹²³⁴^ORCID

Affiliation:

1. College of Material, Chemistry and Chemical Engineering

2. Hangzhou Normal University

3. Hangzhou 310036

4. P. R. China

5. Faculty of Materials Science and Chemical Engineering

Abstract

Non-precious metal copper-catalyzed asymmetric 1,4-hydrosilylation of β-aryl or β-alkyl-substituted N-aryl β-enamino esters proceeded in air in high yields and excellent enantioselectivities (26 examples, 90–98% ee).

Funder

National Natural Science Foundation of China

Natural Science Foundation of Zhejiang Province

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/RA/C9RA01203F

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