Entropy-controlled biradical–quinoid isomerization of a π-conjugated delocalized biradical
Author:
Affiliation:
1. Department of Chemistry
2. School of Science and Engineering
3. Aoyama Gakuin University
4. Sagamihara
5. Japan
6. Itoh Optical Industrial Co., Ltd.
7. Gamagori
8. Graduate School of Science
9. Hiroshima University
10. Higashi-Hiroshima
Abstract
The valence isomerization from the photogenerated biradical to the quinoid species is observed for the photochromic dimer of imidazolyl radicals.
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2015/CP/C4CP04606D
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3. Hartree-Fock descriptions of 1,3-dipoles. Zwitterions, 1,3-diradicals, or hypervalent species?
4. Singlet Biradical → Singlet Zwitterion Optical Transition in a Twisted Olefin
5. An Accurate Description of the Bergman Reaction Using Restricted and Unrestricted DFT: Stability Test, Spin Density, and On-Top Pair Density
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