Characterization of the charge transfer luminescence of the [WO<sub>6</sub>]<sup>6−</sup> octahedron in Ca<sub>3</sub>WO<sub>6</sub> and the [WO<sub>5</sub>]<sup>4−</sup> square pyramid in Ca<sub>3</sub>WO<sub>5</sub>Cl<sub>2</sub>-Reference-Cited by-同舟云学术

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Characterization of the charge transfer luminescence of the [WO₆]⁶⁻ octahedron in Ca₃WO₆ and the [WO₅]⁴⁻ square pyramid in Ca₃WO₅Cl₂

Published:2022 Issue:39 Volume:24 Page:24203-24211
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Kitagawa Yuuki¹^ORCID,Takemura Shota²^ORCID,Hirai Daigorou³^ORCID,Hiroi Zenji³^ORCID,Ueda Jumpei¹^ORCID,Tanabe Setsuhisa¹^ORCID

Affiliation:

1. Graduate School of Human and Environmental Studies, Kyoto University, Sakyo-ku, Kyoto 606-8501, Japan

2. Luminescent Materials Group, National Institute for Materials Science (NIMS), Tsukuba, Ibaraki 305-0044, Japan

3. Institute for Solid State Physics, University of Tokyo, Kashiwa, Chiba 277-8581, Japan

Abstract

The five-fold square pyramid caused by Cl− introduction brings about an inconsistent energy shift of the charge transfer excited states.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP02753D

Reference39 articles.

1. Luminescence of calcium tungstate crystals

2. Luminescent sites in CaWO4 and CaWO4 : Pb crystals

3. Some Aspects of the Luminescence of Solids

4. The luminescence of magnesium tungstate dihydrate, MgWO4·2H2O

5. Luminescence of Lead Molybdate and Lead Tungstate. I. Experimental

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