Characterization of the charge transfer luminescence of the [WO6]6− octahedron in Ca3WO6 and the [WO5]4− square pyramid in Ca3WO5Cl2

Author:

Kitagawa Yuuki1ORCID,Takemura Shota2ORCID,Hirai Daigorou3ORCID,Hiroi Zenji3ORCID,Ueda Jumpei1ORCID,Tanabe Setsuhisa1ORCID

Affiliation:

1. Graduate School of Human and Environmental Studies, Kyoto University, Sakyo-ku, Kyoto 606-8501, Japan

2. Luminescent Materials Group, National Institute for Materials Science (NIMS), Tsukuba, Ibaraki 305-0044, Japan

3. Institute for Solid State Physics, University of Tokyo, Kashiwa, Chiba 277-8581, Japan

Abstract

The five-fold square pyramid caused by Cl introduction brings about an inconsistent energy shift of the charge transfer excited states.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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