A reductive Sandmeyer-type reaction for the synthesis of sulfoxides from anilines under photocatalysis

Author:

Peng Gangqi1,Cheng Hao1,Cheng Xiya1,He Yang1,An Yuanyuan1ORCID,Wu Jie23ORCID,Zheng Danqing1ORCID

Affiliation:

1. State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, South Puzhu Road 30, Nanjing 210009, China

2. School of Pharmaceutical and Chemical Engineering & Institute for Advanced Studies, Taizhou University, 1139 Shifu Avenue, Taizhou 318000, China

3. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China

Abstract

A reductive Sandmeyer-type sulfinylation reaction of aryldiazonium salts with sodium sulfinates is reported, affording a range of valuable sulfoxides in a radical substitution pathway.

Funder

Natural Science Foundation of Jiangsu Province

Nanjing Tech University

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

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