Electrocatalytic dehydrogenative and defluorinative coupling between aldehyde-derived <i>N</i>,<i>N</i>-dialkylhydrazones and fluoromalonates: synthesis of 2-pyrazolines-Reference-Cited by-同舟云学术

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Electrocatalytic dehydrogenative and defluorinative coupling between aldehyde-derived N,N-dialkylhydrazones and fluoromalonates: synthesis of 2-pyrazolines

Published:2024 Issue:21 Volume:22 Page:4269-4273
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Noël Florent¹,El Kaïm Laurent²,Masson Géraldine¹³^ORCID,Claraz Aurélie¹^ORCID

Affiliation:

1. Institut de Chimie des Substances Naturelles, CNRS, Univ. Paris-Saclay, 1 Avenue de la Terrasse, 91198 Gif-sur-Yvette Cedex, France

2. Laboratoire de Synthèse Organique (LSO-UMR 76523), CNRS, Ecole Polytechnique, ENSTA-Paris, Institut Polytechnique de Paris, 828 Bd des Maréchaux, 91128 Palaiseau Cedex, France

3. HitCat, Seqens-CNRS Joint Laboratory, Seqens'Lab, Porcheville, France

Abstract

An electrocatalytic oxidative formal (4 + 1)-cycloaddition between hydrazones and fluoromalonates furnished 2-pyrazolines through triple C–H bond cleavage and one defluorination.

Funder

Centre National de la Recherche Scientifique

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/OB/D4OB00588K

Reference73 articles.

1. Recent advances in the therapeutic applications of pyrazolines

2. Pyrazoline Containing Compounds as Therapeutic Targets for Neurodegenerative Disorders

3. New 2-Pyrazoline and Hydrazone Derivatives as Potent and Selective Monoamine Oxidase A Inhibitors

4. Synthesis and studies on antidepressant and anticonvulsant activities of some 3-(2-furyl)-pyrazoline derivatives

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