Inner versus outer sphere metal-monoamide complexation: ramifications for tetravalent & hexavalent actinide selectivity-Reference-Cited by-同舟云学术

Inner versus outer sphere metal-monoamide complexation: ramifications for tetravalent & hexavalent actinide selectivity

Published:2018 Issue:7 Volume:42 Page:5415-5424
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

McCann Kevin¹²³⁴,Sinkov Sergey I.⁵⁶⁴,Lumetta Gregg J.⁵⁶⁴^ORCID,Shafer Jenifer C.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Colorado School of Mines

3. Golden

4. USA

5. Pacific Northwest National Laboratory

6. Richland

Abstract

Extraction of tetravalent and hexavalent plutonium by straight and branched chained monoamides was studied using UV-vis spectroscopy. These results suggest straight monoamides recover outer-sphere species, while branched chain monoamides recover inner-sphere species.

Funder

Nuclear Energy University Program

Workforce Development for Teachers and Scientists

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/NJ/C7NJ04851C

Reference36 articles.

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2. An overview and historical look back at the solvent extraction using nitrogen donor ligands to extract and separate An(III) from Ln(III)