Radiation-grafted anion-exchange membranes for CO<sub>2</sub> electroreduction cells: an unexpected effect of using a lower excess of <i>N</i>-methylpiperidine in their fabrication-Reference-Cited by-同舟云学术

Radiation-grafted anion-exchange membranes for CO₂ electroreduction cells: an unexpected effect of using a lower excess of N-methylpiperidine in their fabrication

Published:2023 Issue:38 Volume:11 Page:20724-20740
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Willson Terry R.¹,Giron Rodriguez Carlos A.²,Xu Qiucheng²^ORCID,Frow Jordan³,Foglia Fabrizia⁴,Smith Keenan⁴,Ravikumar Ravikumar⁵,Vinothkannan Mohanraj⁵,Mahmoudi Najet⁶^ORCID,Salam Ihtasham¹,Periasamy Arun Prakash¹,Whelligan Daniel K.¹^ORCID,Mamlouk Mohamed⁵,Lin Hungyen³^ORCID,Seger Brian²^ORCID,Varcoe John R.¹^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, The University of Surrey, Guildford GU2 7XH, UK

2. Department of Physics, The Technical University of Denmark, Fysikvej, 312, DK-2800 Kgs. Lyngby, Denmark

3. School of Engineering, Lancaster University, Lancaster LA1 4YW, UK

4. Department of Chemistry, Christopher Ingold Laboratory, University College London, London WC1H 0AJ, UK

5. School of Engineering, Merz Court, Newcastle University, NE1 7RU, UK

6. ISIS Neutron and Muon Source, Science & Technology Facilities Council, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Chilton OX11 0QX, UK

Abstract

Radiation-grafted methylpiperidinium anion-exchange membranes fabricated using different amine excesses are spectroscopically similar but possess different nano-morphological and hydration responses.

Funder

Engineering and Physical Sciences Research Council

Horizon 2020 Framework Programme

Royal Academy of Engineering

Villum Fonden

Centre for Global Eco-Innovation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/TA/D3TA04915A

Reference41 articles.

1. Designing anion exchange membranes for CO2 electrolysers

2. How membrane characteristics influence the performance of CO₂ and CO electrolysis

3. High carbonate ion conductance of a robust PiperION membrane allows industrial current density and conversion in a zero-gap carbon dioxide electrolyzer cell

4. Insights into the carbon balance for CO2 electroreduction on Cu using gas diffusion electrode reactor designs

5. An alkaline polymer electrolyte CO2 electrolyzer operated with pure water