Synthesis of acrylic acid and acrylic esters via oxidation and oxidative alkoxylation of acrolein under mild conditions with selenium-modified microgel catalysts

Author:

Kharandiuk Tetiana12ORCID,Tan Kok H.12,Kubitska Iryna3,Al Enezy-Ulbrich Miriam Aischa12,Ivasiv Volodymyr3ORCID,Nebesnyi Roman3,Potemkin Igor I.1ORCID,Pich Andrij124ORCID

Affiliation:

1. DWI Leibniz Institute for Interactive Materials e.V, Forckenbeckstraße 50, 52074, Aachen, Germany

2. Institute of Technical and Macromolecular Chemistry, RWTH Aachen University, Worringerweg 2, 52074, Aachen, Germany

3. Technology of Organic Products Department, Lviv Polytechnic National University, 12 S. Bandera St., 79013, Lviv, Ukraine

4. Aachen Maastricht Institute for Biobased Materials (AMIBM), Maastricht University, Brightlands Chemelot Campus, Urmonderbaan 22, 6167 RD Geleen, The Netherlands

Abstract

Systematic studies of the performance of Se-modified microgel catalysts in acrolein oxidation and oxidative alkoxylation under green reaction conditions were conducted to afford high yields and selectivity of the process.

Funder

Volkswagen Foundation

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Fluid Flow and Transfer Processes,Process Chemistry and Technology,Chemical Engineering (miscellaneous),Chemistry (miscellaneous),Catalysis

Reference39 articles.

1. Catalytic routes towards acrylic acid, adipic acid and ε-caprolactam starting from biorenewables

2. Activity Hysteresis during Cyclic Temperature-Programmed Reactions in the Partial Oxidation of Acrolein to Acrylic Acid

3. A. H.-J.Weissermel Klaus , Industrial Organic Chemistry, 3rd , Completely Revised Edition, Wiley-VCH , Weinheim , 3rd edn, 2008

4. J. S.Plotkin , H. A.Wittcoff and B. G.Reuben , Industrial Organic Chemicals , Weinheim , 3rd edn, 2012

5. Direct oxidative transformation of glycerol to acrylic acid over Nb-based complex metal oxide catalysts

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