One-step synthesis of indolizino[3,4,5-ab]isoindoles by manganese(i)-catalyzed C–H activation: structural studies and photophysical properties

Author:

Cembellín Sara12ORCID,Maisuls Iván3ORCID,Daniliuc Constantin G.1ORCID,Osthues Helena4ORCID,Doltsinis Nikos L.4ORCID,Strassert Cristian A.3ORCID,Glorius Frank1ORCID

Affiliation:

1. Organisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Corrensstraße 40, 48149 Münster, Germany

2. Organic Chemistry Department, Universidad Complutense de Madrid, 28040 Madrid, Spain

3. Institute for Inorganic and Analytical Chemistry, Center for Nanotechnology, Center for Soft Nanoscience, Cells in Motion Interfaculty Centre, Westfälische Wilhelms-Universität Münster, Heisenbergstraße 11, 48149 Münster, Germany

4. Institut für Festkörpertheorie and Center for Multiscale Theory and Computation, Westfälische Wilhelms-Universität Münster, Wilhelm-Klemm-Straße 10, 48149 Münster, Germany

Abstract

A selective synthesis of relevant fluorescent compounds, indolizino[3,4,5-ab]isoindoles (INIs), through a Mn(i)-catalyzed C–H activation on readily available 2-phenylpyridines is described.

Funder

Alexander von Humboldt-Stiftung

Deutsche Forschungsgemeinschaft

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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