Impact of deboronation on the electronic characteristics of closo-o-carborane: intriguing photophysical changes in triazole-appended carboranyl luminophores-Reference-Cited by-同舟云学术

Impact of deboronation on the electronic characteristics of closo-o-carborane: intriguing photophysical changes in triazole-appended carboranyl luminophores

Published:2021 Issue:9 Volume:50 Page:3207-3215
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kim Mingi¹²³⁴⁵,Im Sehee¹²³⁴⁵,Ryu Chan Hee¹²³⁴⁵,Lee Seok Ho¹²³⁴⁵,Hong Ju Hyun¹²³⁴⁵,Lee Kang Mun¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Institute for Molecular Science and Fusion Technology

3. Kangwon National University

4. Chuncheon

5. Republic of Korea

Abstract

A deboronation reaction of 1,2,4-triazole-appended closo-o-carboranyl luminophores to nido-o-carboranes results in a ratiometric change in the emission color from deep-blue to sky-blue, in addition to intense turn-on responses.

Funder

National Research Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT04038J

Reference68 articles.

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2. Boron in Drug Discovery: Carboranes as Unique Pharmacophores in Biologically Active Compounds

3. Electrochemistry and Photoluminescence of Icosahedral Carboranes, Boranes, Metallacarboranes, and Their Derivatives