Hydration and ion pair formation in common aqueous La(iii) salt solutions – a Raman scattering and DFT study-Reference-Cited by-同舟云学术

Hydration and ion pair formation in common aqueous La(iii) salt solutions – a Raman scattering and DFT study

Published:2015 Issue:1 Volume:44 Page:295-305
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Rudolph Wolfram W.¹²³⁴,Irmer Gert⁵⁶⁷⁴

Affiliation:

1. Medizinische Fakultät der TU Dresden

2. Institut für Virologie im MTZ

3. 01307 Dresden

4. Germany

5. Technische Universität Bergakademie Freiberg

6. Institut für Theoretische Physik

7. 09596 Freiberg

Abstract

Left hand side: Raman spectrum of a 0.622 mol L⁻¹La(ClO₄)₃(aq). Weak, polarized band at 343 cm⁻¹assigned to symmetric La–O stretch of [La(OH₂)₉]³⁺. Bands at 463 and 630 cm⁻¹due to ClO₄⁻(aq). The inset shows the isotropic band in more detail. Right hand side: Structure of [La(OH₂)₉]³⁺(symmetryD₃).

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT03003F

Reference50 articles.

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