Ambidentate bonding and electrochemical implications of pincer-type pyridylidene amide ligands in complexes of nickel, cobalt and zinc

Author:

Melle Philipp1234,Ségaud Nathalie1234ORCID,Albrecht Martin1234ORCID

Affiliation:

1. Department für Chemie und Biochemie

2. Universität Bern

3. CH-3012 Bern

4. Switzerland

Abstract

Pincer-type tridentate pyridyl bis(pyridylidene amide) (pyPYA2) ligand systems were coordinated to the Earth-abundant first row transition metals nickel, cobalt and zinc, revealing ambidentate N,N,N and O,N,O coordination behavior.

Funder

FP7 Ideas: European Research Council

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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