Structure, optical properties, and catalytic applications of alkynyl-protected M<sub>4</sub>Rh<sub>2</sub>(M = Ag/Au) nanoclusters with atomic precision: a comparative study-Reference-Cited by-同舟云学术

Structure, optical properties, and catalytic applications of alkynyl-protected M₄Rh₂(M = Ag/Au) nanoclusters with atomic precision: a comparative study

Published:2023 Issue:27 Volume:52 Page:9441-9447
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Chen Leyi¹,Sun Fang²,Shen Quanli¹,Wang Lei¹,Liu Yonggang¹,Fan Hao¹,Tang Qing²^ORCID,Tang Zhenghua¹^ORCID

Affiliation:

1. New Energy Research Institute, School of Environment and Energy, South China University of Technology, Guangzhou Higher Education Mega Centre, Guangzhou, 510006, China

2. School of Chemistry and Chemical Engineering, Chongqing Key Laboratory of Theoretical and Computational Chemistry, Chongqing University, Chongqing, 401331, China

Abstract

We report two atomically precise alkynyl-protected Ag4Rh2and Au4Rh2nanoclusters, which have markedly different optical features and catalytic properties toward HER and 4-nitrophenol reduction.

Funder

South China University of Technology

Chongqing Science and Technology Commission

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT01326J

Reference38 articles.

1. Shell engineering to achieve modification and assembly of atomically-precise silver clusters