Dipotassiumtetrachloride-bridged dysprosium metallocenes: a single-molecule magnet-Reference-Cited by-同舟云学术

Dipotassiumtetrachloride-bridged dysprosium metallocenes: a single-molecule magnet

Published:2023 Issue:42 Volume:52 Page:15326-15333
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Arumugam Selvakumar¹,Schwarz Björn²^ORCID,Ravichandran Prathap¹,Kumar Sunil¹^ORCID,Ungur Liviu³^ORCID,Mondal Kartik Chandra¹^ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Technology Madras, Chennai, India

2. Institute for Applied Materials – Energy Storage Systems (IAM-ESS), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

3. Department of Chemistry, National University of Singapore, Singapore

Abstract

The dinuclear Dy(iii)-metallocene, weakly coupled via a K2Cl4 bridge, displays slow relaxation of magnetization below 17 K under zero applied dc field via KD3 energy levels with an energy barrier of 136.9/133.7 cm−1 on the Dy sites.

Funder

Science and Engineering Research Board

Ministry of Education - Singapore

National Supercomputing Centre Singapore

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT01325A

Reference95 articles.

1. The rare earth elements: fundamental and applications , ed. D. A. Atwood , University of Kentucky , Lexington, KY, USA , 2012