Acyclic 1,2-dimagnesioethanes/-ethene derived from magnesium(i) compounds: multipurpose reagents for organometallic synthesis-Reference-Cited by-同舟云学术

Acyclic 1,2-dimagnesioethanes/-ethene derived from magnesium(i) compounds: multipurpose reagents for organometallic synthesis

Published:2019 Issue:11 Volume:10 Page:3208-3216
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Dange Deepak¹²³⁴,Gair Andrew R.¹²³⁴⁵,Jones Dafydd D. L.¹²³⁴^ORCID,Juckel Martin¹²³⁴,Aldridge Simon⁵⁶⁷⁸⁹^ORCID,Jones Cameron¹²³⁴^ORCID

Affiliation:

1. School of Chemistry

2. Monash University

3. VIC

4. Australia

5. Inorganic Chemistry Laboratory

6. Department of Chemistry

7. University of Oxford

8. Oxford

9. UK

Abstract

The sometimes redox reversible 1,2-additions of magnesium(i) dimers across several alkenes and one alkyne yield 1,2-dimagnesioethanes and a 1,2-dimagnesioethene. Treatment of these with bulky amido metal halide precursors affords novel products via three reactivity modes.

Funder

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC00200F

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