Enhanced solar water splitting of BiVO4 photoanodes by in situ surface band edge modulation

Author:

Song Kai123,Hou Huilin3ORCID,Gong Chuangchuang12,Gao Fengmei3,Zhang Dongdong3,Zhi Fang3ORCID,Yang Weiyou3ORCID,He Fang12

Affiliation:

1. School of Materials Science and Engineering, Tianjin University, Tianjin, 300350, P. R. China

2. Tianjin Key Laboratory of Composite and Functional Materials, Tianjin University, Tianjin, 300350, P. R. China

3. Institute of Micro/Nano Materials and Devices, Ningbo University of Technology, Ningbo, 315211, P. R. China

Abstract

In this work, the surface band edge of the BiVO4 photoanode is modulated by an in situ gas-phase cation exchange method, in which some of the Bi atoms on the surface are replaced by V atoms to form a V-rich surface.

Funder

China Postdoctoral Science Foundation

National Natural Science Foundation of China

Natural Science Foundation of Ningbo

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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