High energy density Na-metal batteries enabled by a tailored carbonate-based electrolyte

Author:

Chen Jiawei1,Peng Yu1,Yin Yue1,Liu Mingzhu2,Fang Zhong1,Xie Yihua1,Chen Bowen3,Cao Yongjie1ORCID,Xing Lidan2ORCID,Huang Jianhang1ORCID,Wang Yonggang1ORCID,Dong Xiaoli1ORCID,Xia Yongyao1ORCID

Affiliation:

1. Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Institute of New Energy, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), Fudan University, Shanghai 200433, China

2. National and Local Joint Engineering Research Center of MPTES in High Energy and Safety LIBs, Engineering Research Center of MTEES (Ministry of Education), Research Center of BMET (Guangdong Province), Key Lab. of ETESPG (GHEI), Innovative Platform for ITBMD (Guangzhou Municipality), School of Chemistry, South China Normal University, Guangzhou 510006, China

3. i-Lab, CAS Center for Excellence in Nanoscience, Suzhou Institute of Nano-Tech and Nano-Bionics (SINANO), Chinese Academy of Sciences (CAS), Suzhou 215123, China

Abstract

A carbonate-based electrolyte is well-designed via a multifunctional lithium difluorobis(oxalato) phosphate (LiDFBOP) additive, endowing 4.5 V sodium metal batteries with high energy density, excellent cycling stability and a wide temperature range.

Funder

Natural Science Foundation of Shanghai

National Natural Science Foundation of China

National Key Research and Development Program of China

Shanghai Education Development Foundation

Shanghai Municipal Education Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

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