Origin of hydrogen evolution activity on MS2 (M = Mo or Nb) monolayers

Author:

Chen Xiaobo12345,Gu Yu12345,Tao Guohua6785,Pei Yanli91011125,Wang Guangjin1314155,Cui Ni12345

Affiliation:

1. Department of Physics and Siyuan Laboratory

2. College of Science and Engineering

3. Jinan University

4. Guangzhou 510632

5. China

6. Shenzhen Key Laboratory of New Energy Materials by Design

7. Peking University

8. Shenzhen 518055

9. State Key Lab of Optoelectronics Materials & Technologies

10. School of Physics & Engineering

11. Sun Yat-Sen University

12. Guangzhou 510275

13. College of Chemistry and Materials Science

14. Hubei Engineering University

15. Xiaogan 432000

Abstract

The Volmer reaction is thermodynamically governed by adiabatic electron and proton affinities, and the high HER activity of 2D MS2 monolayers comes from their large adiabatic electron affinities.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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